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All Physics help!!

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Good day, I have a question here: to find refractive index, we use sin i/sin r. But there are cases when we have to switch to sin r/sin i. I would like to ask, when do we switch?
 
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it depends on from where does the ray comes if for example from air to a block then sin i/sinr, from block to air sinr/sini
 
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