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Chemistry MCQ thread...

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hassam said:
Which of the following statement(s) is/are true?
1 When SiCl4 is added to water, a precipitate is formed.
2 sulfur has a higher melting point than phosphorus because the intermolecular
attractions are stronger.
3 When AlCl3 is dissolved in water, [Al(H2O)5(OH)]2+(aq) is one of the ions
formed.

B?
1 and 2 are right, I think.
 
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Anonymousx3 said:
hassam said:
Which of the following statement(s) is/are true?
1 When SiCl4 is added to water, a precipitate is formed.
2 sulfur has a higher melting point than phosphorus because the intermolecular
attractions are stronger.
3 When AlCl3 is dissolved in water, [Al(H2O)5(OH)]2+(aq) is one of the ions
formed.

B?
1 and 2 are right, I think.

A. All 3 are correct.

Xthegreat said:
nope, its 2 and 3.

SiCl4 dissolves in water to give a strong acid, no ppt

It also forms SiO2. Water can't dissolve it.
 
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Doesn't the [Al(H2O)5OH]2+ ion form when Al2Cl6 is dissolved in water, not AlCl3?
Or are they the same thing and I'm just confusing myself?
 
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Al2Cl6 is formed due to dimerization of AlCl3, so they should be same things . . .

Correct me if i m wrong!! :D
 
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hassam said:
Which of the following statement(s) is/are true?
1 When SiCl4 is added to water, a precipitate is formed.
2 sulfur has a higher melting point than phosphorus because the intermolecular
attractions are stronger.
3 When AlCl3 is dissolved in water, [Al(H2O)5(OH)]2+(aq) is one of the ions
formed.
i m not sure about 1 but statements 2 and 3 are correct
 
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Anonymousx3 said:
Doesn't the [Al(H2O)5OH]2+ ion form when Al2Cl6 is dissolved in water, not AlCl3?
Or are they the same thing and I'm just confusing myself?

No, it also forms when AlCl3 dissolves in water. First of all [Al(H2O)6]3+ forms, this ion is acidic, so then it forms [Al(H2O)5OH]2+

MHHaider707 said:
Al2Cl6 is formed due to dimerization of AlCl3, so they should be same things . . .

Correct me if i m wrong!! :D
Right.
 
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1 is also correct as on dissolving in water SiCl4 will give HCl and SiO2....

SiO2 is insoluble so it will be the precipitate!!

SiCl4 + 2H2O------> SiO2 + 4HCl
 
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xHazeMx said:
why is it 1 only???

Because benzoic acid will be formed from 2, which is readily soluble in hot water, but is poorly soluble in cold one.

Option number 3 is a ketone, so that can't be oxidised.
 
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