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same thing happened to me PhyZac..worked with me perfectly with the cations but not with the anions :S:SWaalikum Assalamu Wa Rahmatullahi Wa Barakatoho.
Well, for the cathode it worked perfectly.
Those cation which are less reactive than hydrogen (that is +ve E values) will form, as in Ag, while if not, then hydrogen forms.
Anion din't work with me either. But I always learned the when sulphate is there O2 is formed. Sorry. Rest I am confused too.