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Chemistry: Post your doubts here!

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Hi can someone please help with qn 2 a)
I've the exam tmr,,
Yeah this was a time consuming question. Anyway so this is what I did. You do the same thing for the diethyl ether, you have to write out the equation and all. Obviously all this working is not required but I cant do any calculations without writing it down.
 

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The answer to this is B.
Why isn't it A? as the question says ' some covalent character' doesn't this imply least covalent character?Screen Shot 2014-11-21 at 6.46.46 PM.png
 
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Why are we dividing y by 2? although y is the enthalpy change of reaction and it doesn't have to be per mole?jpeg-1.jpeg
 
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The answer to this is B.
Why isn't it A? as the question says ' some covalent character' doesn't this imply least covalent character?View attachment 49173
NaCl is a crystal ionic lattice. It possesses only ionic bonds.


MgCl2 too is a crystal lattice. There are ionic bonds between Magnesium and Chlorine, because Mg is a metal, and Cl is a non-metal. However, since there are two atoms of chlorine in every molecule of MgCl2, there has to be some bonding between Cl2 as well. Thus, between Clorine, there will be Covalent bonds (Instantaneous Induced Dipole Forces of Attraction). Thus the compound will exhibit SOME Covalent Character.
 
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NaCl is a crystal ionic lattice. It possesses only ionic bonds.


MgCl2 too is a crystal lattice. There are ionic bonds between Magnesium and Chlorine, because Mg is a metal, and Cl is a non-metal. However, since there are two atoms of chlorine in every molecule of MgCl2, there has to be some bonding between Cl2 as well. Thus, between Clorine, there will be Covalent bonds (Instantaneous Induced Dipole Forces of Attraction). Thus the compound will exhibit SOME Covalent Character.
Right, but isn't it true that covalent character is due to the polarising power of the metal ion? and Na is less polarising power then Mg because of less charge so it would have less covalent character while Mgcl2 will have more :S so shouldn't the answer be A :(
 
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Right, but isn't it true that covalent character is due to the polarising power of the metal ion? and Na is less polarising power then Mg because of less charge so it would have less covalent character while Mgcl2 will have more :S so shouldn't the answer be A :(
o_Oo_Oo_Oo_O
Polarizing effect is due to the difference in the electronegativity. Covalent character is not due to the polarizing power of the metal ion. It isn't necessary. Covalent character is present in HCl. There is no metal ion in this case.
 
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i think you haven't came across it yet :0 because there is no covalent character in covalent compounds.. its a term used for ionic compounds
 
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W13qp 21 question 4 part iii
Mj 12 qp 21 question 2 part iv.
Anyone? I always have problem in these kind of questions.
 
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can u indicate on the picture the chiral carbon and also how u identified A and B to be cis trans isomers. I find these structures very confusing nd can't really find the isomers in them.
thankyou ۔
 
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