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Chemistry: Post your doubts here!

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Does any know the reason why incoming groups cannot be directed to 3 because of Methyl??
 
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Does any know the reason why incoming groups cannot be directed to 3 because of Methyl??
I wrote that methyl is electron donating so other intermediates were more stable as the + charge was directly placed on the C atom next to methyl
 
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What did you guys write for the Le Chatelier’s?
Also did you write the complex in table like [Ni(CO)4]^2+ or is it only written like this [NiCO4]^2+
 
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