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Chemistry: Post your doubts here!

Messages
325
Reaction score
215
Points
53

21. The functional groups that react with Na are CO2H and OH, so three of any of these should be present in the compound. B and D are ruled out. NaOH will react with CO2H, so there should be 1 CO2H and 2 OH groups.
28. The energy profile shows a reaction that has 2 steps, one endothermic and another exothermic. That means in the reaction a bond is broken and another bond is formed.
38. Find the molecular masses of butanone, butanoic acid and 2-methyl propanoic acid. Then use actual yield/calculated yield x 100 and see if you get 60 % for all.
36. Work this out using Le Chatelier's principle. A higher pressure obviously means a higher cost. SO3 is on the side of the fewer molecules, and high pressures favour the sides of fewer molecules. A high pressure will automatically result in an increased rate because collisions will increase, and that'll increase the chance of successful collisions.
 
Messages
325
Reaction score
215
Points
53

وعليكم السلام
7 and 11:
Draw ICE charts, i.e. initial moles, change in moles and equilibrium moles, for ALL the options (A, B, C and D). Then see which one has x + 2/x for its final moles.
For example, 7 D:
s4J2eot.jpg

We divide the equilibrium moles by 2 because the question says that the final moles of R are x, so we need to make the final moles of R = x.
 
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28

Q.11:
In Hydrazine, the N-N is a single bond and not a triple bond. Simply because it has a high activation energy ie B.
Q.23:
The product produced as a result of oxidation produces orange ppt with 2,4 dinitrophenyl hydrazine means that it contains a carbonyl carbon. ie it is either a ketone or an aldehyde. Since it does not give a positive test with tollens reagent, it is a ketone.
Ketones are produced by oxidation of secondary alcohol. Butan-2-ol is a secondary alcohol hence B is the answer.
Q.36:
the first two options are correct. NaCl dissolves in water and produces Na and Cl ions and the pH is 7 ie neutral. Since 1 and 2 are right, B is right.
 
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http://papers.xtremepapers.com/CIE/Cambridge International A and AS Level/Chemistry (9701)/9701_w12_qp_13.pdf
Q5,
combustion is exothermic right?
C-H = 410
C -(triple-bond)- C = 840
O-H = 460
C=O = 740
O=O = 496
acha g, now all you have to is put all the exothermic things one side minus the endothermic on the other side, bond breaking is endothermic and bond forming is exothermic
so we have
endothermic - exothermic, since exothermic is negative

[2 (C-H) + ( C -(triple-bond)- C ) + 2.5 (O=O)] - [4 (C=O) + 2 (O-H)]
[2(410) + (840) + 2.5 (496)] - [4 (740) +2 (460)]
2900 - 3880
-980
so answer is A
 
Messages
325
Reaction score
215
Points
53
Messages
325
Reaction score
215
Points
53
Messages
325
Reaction score
215
Points
53

1. Just multiply the moles by Avogrado's constant.
40. The compound is an ester. When ester are hydrolysed with NaOH, the alcohol is given and the sodium salt of carboxylic acid is given.
 
Messages
325
Reaction score
215
Points
53

21. The functional groups that react with Na are CO2H and OH, so three of any of these should be present in the compound. B and D are ruled out. NaOH will react with CO2H, so there should be 1 CO2H and 2 OH groups.
22. Find the molecular mass of the products of the hydrolysis of ethyl propanoate. Then find the % by mass.
23. The compound is an ester and will get hydrolysed by the acid.
 
Messages
325
Reaction score
215
Points
53
16. This is something you have to memorise. Cl2 + cold, dilute NaOH will give a ClO- ion (oxidation state = +3) and Cl2 + hot, concentrated NaOH will give a ClO3- ion (oxidation state = +5).
20. Find the molecular masses of the products of propyl propanoate. The find the % by mass of each compound.
28. -NH2 from NH3 substitutes one Br atom. NH2 is a nucleophile too, and has to be close to the other C-Br bond so that it can attack it. 1,5 is closer than 1,4.
 
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35
Reaction score
19
Points
18
An organic compound J reacts with sodium to produce an organic ion with a charge of –3.
J reacts with NaOH(aq) to produce an organic ion with a charge of –1.
What could be the structural formula of J?
A HO2CCH(OH)CH2CO2H
B HO2CCH(OH)CH2CHO
C HOCH2CH(OH)CH2CO2H
D HOCH2COCH2CHO
 
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