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Chemistry: Post your doubts here!

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http://papers.xtremepapers.com/CIE/Cambridge International A and AS Level/Chemistry (9701)/9701_s09_qp_1.pdf. Q9 ans A , q15 ans A , q17 ans D ,q19 ans D , q20 ans C q 35 ans B
Sorry they are a lot :D
Q15. Check that the oxidation state of silver before and after the reaction is +1, it means that it is neither oxidized or reduced. This effectively eliminates options B, C and D. silver chloride is insoluble and the silver complex formed is soluble.

Q9. less electropositve means less easily oxidised. It is harder to oxidise Ag (into Ag+ ions) than Cu into Cu2+ ions, so Ag remains in solid state while Cu dissolves.

Q17.
A: SO3 is acidic and NH3 is basic
B: There is a dative bond between N and 1 of the H in NH4+
C: Ionic bond between ammonium ion and sulfate ion
D: No change in oxidation state of the atoms

Q19. Hard to describe by typing, most easily missed out by students are the 3 chiral carbons that each contain a H which are not reflected in the diagram (check the "Y junctions")

Q20. all 3 C=C bonds are capable of cis-trans isomerism, so max isomers = 2^3 = 8

Q35.
1. Refactory linings require substances to withstand high temperatures
2. The carbonate will react with acidic gases to form solids and prevent the acidic gases from being released into the atmosphere.
 
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In direction of oxidation,

Primary alcohol functional group --> aldehyde function group --> acid functional group

secondary alcohol functional group --> ketone functional group

Q40.
1. (Correct) 1st compound aldehyde functional group is oxidised to 2nd compound acid group
2. (Correct) 2nd compound ketone functional group is reduced to 3rd compound alcohol group
3. (Correct) 1st compound alcohol group is oxidised to 2nd compound ketone group
 
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Q3. I don't have the data booklet at hand now, but you can look it up and add the 1st and 2nd IE of Al. Then see which of the 4 options give then same total value as Al.

Q10. D: Combustion of CH4 to CO2 and H2O is exothermic, so is the formation of N2 due to forming of triple bonds.

Q29. Option C is actually an ester bond on the left, not an acid functional group.

Q39.
Ethanol acts as base and gains proton to form CH3CH2OH2+
Conc H2SO4 acts as an acid and loses proton to form HSO4-
So statement 2 and 3 are correct
 
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Q3. I don't have the data booklet at hand now, but you can look it up and add the 1st and 2nd IE of Al. Then see which of the 4 options give then same total value as Al.

Q10. D: Combustion of CH4 to CO2 and H2O is exothermic, so is the formation of N2 due to forming of triple bonds.

Q29. Option C is actually an ester bond on the left, not an acid functional group.

Q39.
Ethanol acts as base and gains proton to form CH3CH2OH2+
Conc H2SO4 acts as an acid and loses proton to form HSO4-
So statement 2 and 3 are correct
Thanks alot :D
 
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Can any one explain how SO2 inhibits aerobic bacteria in preserving food?
And also the concept of dipole moment!
Use of so2 in food preservation : So2 since is bacteriostatic, is used in food preservation. Its reducing character when moist helps it to be used as a food preservative. They (so2 and sulphides) inhibit the oxidation of food compounds eg:unsaturated fats and also act as acids to restrict the growth of molds and aerobic bacteria.

Dipole moment is the shifting of shared electron pair towards more electronegative elements.
More electronegative elements like (F , O , N , Cl , S , P, Br)

Note that hydrogen and carbon are less electronegative elements and the difference between them are not much and is not significant.
 
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