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chemistry unit 3 !!! discussion in here !! =p

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guyz this one > propan-1-ol + h2so4 concentrated heated under reflux ! identify the main organic product ?
 
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oh this one too guyz > kI + h2so4 >> gives wat nd wat r the observations ?
 
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gives HI and KHSO4.
HI immediately oxidised to iodine. H2SO4 reduced to hydrogen sulfide
observations;
rotten egg smell and turns lead ethonate paper from white to black.
dude but theres yellow solid formed wats it ?
nd the color of the filter is due to HsO2 ?? why lead ethanoate ??
wats the colour os So2 ?
thnks =p
 
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wat book do u have?? o_O
pearson ! =p
they r all truee:p
yellow solid- KHSO4
Steamy gas- HI
purple vapour- I2
lead ethonate and rotten egg smell is for H2S
pass through aci.potassium dichromate green to orange then SO2
oh ! =p !
okay can you tell me wat do we need to know bout the apearance of so2 nd so3
so2 is being oxidised by k2cr2o7 ? thats why ?
 
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pearson ! =p

oh ! =p !
okay can you tell me wat do we need to know bout the apearance of so2 nd so3
so2 is being oxidised by k2cr2o7 ? thats why ?
pearson umm the one of edexcel AS chemistry by Ann Fullick and Bob Mcduell??
Cr2O7 2-(aq) + 3SO2 (g) + 2H+ (aq) = 2Cr3+ (aq) + 3SO4 2- (aq) H2O (l)
Test for SO32- Warm the sulphite with dilute HCl. using acidified potassium dichromate(VI) solution (or paper). The solution turns green.
for SO4 2- Add barium chloride solution acidified with dilute HCl to the test solution. White precipitate of barium sulphate forms.
 
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wait wat ??

??
2 different answers ?? O.O 0.O

2 Identical answers, just with different focuses on the reaction. And we're both right so :p

H2SO4 is reduced by potassium dichromate to form SO2

Look at the oxidation numbers, +6 to +4.

In SO3 Sulphur is +6 and in SO2 it is +4.

By OILRIG, electrons have been gained, so it has been reduced.

Unless the SO3 has 2- next to it, which you didn't say :p
 
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2 Identical answers, just with different focuses on the reaction. And we're both right so :p

H2SO4 is reduced by potassium dichromate to form SO2

Look at the oxidation numbers, +6 to +4.

In SO3 Sulphur is +6 and in SO2 it is +4.

By OILRIG, electrons have been gained, so it has been reduced.

Unless the SO3 has 2- next to it, which you didn't say :p

=S wat happens if it has 2- ?
 
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pearson umm the one of edexcel AS chemistry by Ann Fullick and Bob Mcduell??
Cr2O7 2-(aq) + 3SO2 (g) + 2H+ (aq) = 2Cr3+ (aq) + 3SO4 2- (aq) H2O (l)
Test for SO32- Warm the sulphite with dilute HCl. using acidified potassium dichromate(VI) solution (or paper). The solution turns green.
for SO4 2- Add barium chloride solution acidified with dilute HCl to the test solution. White precipitate of barium sulphate forms.
idk man just that =p !
the test for so32- is same as so2 ? ya ?
thankss !
ya whose with the pungent smell again so2 ?? =$
 
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