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Chemistry: Post your doubts here!

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924
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Initial: b, 0, 0
Final: b-x, x/2, x/2
Total moles = b-x+x/2+x/2= b
Mole ratio: (b-x)/b, (x/2)/b, (x/2)/b
Partial pressure = p(b-x)/b, px/(2b) px/(2b)

Kp = px/(2b)*px/(2b) / (p(b-x)/b)^2 = D

Alternatively you can realise that we can use concentration and find out Kp expression without taking pressure or mole ratio to consideration, since you can see Kp will have no units as pressure cancels out
 
Messages
924
Reaction score
1,096
Points
153
Messages
479
Reaction score
1,374
Points
153
Which molecules, each with a linear carbon chain, can have an optically active isomer?
I - C3H6BrI
II - C3H4BrI
III - C3H6I2
IV - C3H4Br2

A. I and II only
B. I, II and III only
C. II and III only
D. I, II and IV only


answer is B, explain?
 
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479
Reaction score
1,374
Points
153
Carbon monoxide burns readily in oxygen to form carbon dioxide.
What can be deduced from this information?

1 The +4 oxidation state of carbon is more stable than the +2 state.
2 The standard enthalpy change of formation of carbon dioxide is more negative than that of
carbon monoxide.
3 The value of the equilibrium constant for the reaction, 2CO(g) + O2(g) 2CO2(g), is likely to
be high.


answer is A, i need to know why 3 is correct? explanation please!
 
Messages
1,318
Reaction score
1,374
Points
173
Which molecules, each with a linear carbon chain, can have an optically active isomer?
I - C3H6BrI
II - C3H4BrI
III - C3H6I2
IV - C3H4Br2

A. I and II only
B. I, II and III only
C. II and III only
D. I, II and IV only


answer is B, explain?
upload_2015-5-31_16-23-57.png
For optical isomerism, you need a carbon with a chiral center ( 4 different substituents on the C)
As you can see only 1,2 and 3 have a chrial carbon (marked red)
So it is B
 
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144
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137
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53
Carbon monoxide burns readily in oxygen to form carbon dioxide.
What can be deduced from this information?

1 The +4 oxidation state of carbon is more stable than the +2 state.
2 The standard enthalpy change of formation of carbon dioxide is more negative than that of
carbon monoxide.
3 The value of the equilibrium constant for the reaction, 2CO(g) + O2(g) 2CO2(g), is likely to
be high.


answer is A, i need to know why 3 is correct? explanation please!

It burns readily, so there will be a high concentration of CO2 in the equilibrium mixture. Therefore, applying the formula for equilibrium constant, we can deduce that the value is likely to be high.
 
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31
Reaction score
6
Points
18
Initial: b, 0, 0
Final: b-x, x/2, x/2
Total moles = b-x+x/2+x/2= b
Mole ratio: (b-x)/b, (x/2)/b, (x/2)/b
Partial pressure = p(b-x)/b, px/(2b) px/(2b)

Kp = px/(2b)*px/(2b) / (p(b-x)/b)^2 = D

Alternatively you can realise that we can use concentration and find out Kp expression without taking pressure or mole ratio to consideration, since you can see Kp will have no units as pressure cancels out
Thankyou! :D
 
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