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Oh right! I think I get it. Also, I know this may sound stupid, but for the same question, they said:Q3 b) iii) I think what you say is right. Work done on the system should be positive. Although I explain this from that perspective, I will try to make some sense by explaining it in an alternative way. If you just ignore the words for a moment,
We know the formula W = -P (dV) , where dV is delta volume.
We can write this as W = -P (V2 - V1)
When V2 > V1, dV is positive, hence Work done is negative.
When V2 < V1, dV is negative, hence Work done is positive.
In this case, V2 > V1, so we may say that the Work done is negative.
I think they did a mistake in typing that as work done on the system.
- water vapour volume = 2.96 × 10^–2 m3
- volume occupied by liquid water at 100 °C is 1.87 × 10^–5 m3
So, how would the change in volume (dV) = 2.96 × 10^–2 - 1.87 × 10^–5 ?