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Chemistry MCQ thread...

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aleem420 said:
2 Use of the Data Booklet is relevant to this question.
A typical solid fertiliser for use with household plants and shrubs contains the elements N, P, and
K in the ratio of 15 g : 30 g :15 g per 100 g of fertiliser. The recommended usage of fertiliser is 14 g
of fertiliser per 5 dm3 of water.
What is the concentration of nitrogen atoms in this solution?
A 0.03 mol dm–3
B 0.05 mol dm–3
C 0.42 mol dm–3
D 0.75 mol dm–3

can anyone help me with it???? plz


Ans : A
- the percentage of N is the fertiliser is 15/100 = 0.15%
- in 14g of fertiliser, the amount of N is 14 x 0.15 = 2.1g
- the number of moles of N is 2.1g of N is 2.1/14 = 0.15 mole
- concentration = mole/volume, hence, 0.15/5 = 0.03moldm-3

right?
 
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hassam said:
Which of the following statements is true about hydrogen halides?
A Enthalpy change of formation becomes less exothermic down the group.
B Thermal stability increases down the group.
C Acidity of the corresponding aqueous solution decreases down the group.
D Charge density of cation decreases down the group.
Astatine is below iodine in Group VII.
Which of the following would be a correct prediction for astatine and its compounds?
A Astatine would oxidise chloride to chlorine.
B Potassium astatide would be a white crystalline solid.
C Astatine is insoluble in chloroform.
D Silver astatide reacts with concentrated aqueous ammonia to form a soluble complex.


D for the first one n C for the next.....rite???
 
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hassam said:
Which of the following statements is true about hydrogen halides?
A Enthalpy change of formation becomes less exothermic down the group.
B Thermal stability increases down the group.
C Acidity of the corresponding aqueous solution decreases down the group.
D Charge density of cation decreases down the group.
Astatine is below iodine in Group VII.
Which of the following would be a correct prediction for astatine and its compounds?
A Astatine would oxidise chloride to chlorine.
B Potassium astatide would be a white crystalline solid.
C Astatine is insoluble in chloroform.
D Silver astatide reacts with concentrated aqueous ammonia to form a soluble complex.
both are A right ?
 
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hassam said:
Which of the following statements is true about hydrogen halides?
A Enthalpy change of formation becomes less exothermic down the group.
B Thermal stability increases down the group.
C Acidity of the corresponding aqueous solution decreases down the group.
D Charge density of cation decreases down the group.

D
Astatine is below iodine in Group VII.
Which of the following would be a correct prediction for astatine and its compounds?
A Astatine would oxidise chloride to chlorine.
B Potassium astatide would be a white crystalline solid.
C Astatine is insoluble in chloroform.
D Silver astatide reacts with concentrated aqueous ammonia to form a soluble complex.
B
 
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hassam said:
1st one is A....2nd one b so zishi got 1 rong
Is ever enthalpy change of formation of HI exothermic? :eek: IT IS endothermic.

Charge density: -ve charge/volume

As negative charge decreases down the group and volume increases, so charge density has to decrease. Let me confirm it...
 
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Zishi said:
hassam said:
Which of the following statements is true about hydrogen halides?
A Enthalpy change of formation becomes less exothermic down the group.
B Thermal stability increases down the group.
C Acidity of the corresponding aqueous solution decreases down the group.
D Charge density of cation decreases down the group.

D

* shouldn't the answer for this be A? i though the cation is the same throughout the group? H+ right?
 
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Xthegreat said:
Zishi said:
hassam said:
Which of the following statements is true about hydrogen halides?
A Enthalpy change of formation becomes less exothermic down the group.
B Thermal stability increases down the group.
C Acidity of the corresponding aqueous solution decreases down the group.
D Charge density of cation decreases down the group.

D

* shouldn't the answer for this be A? i though the cation is the same throughout the group? H+ right?
yeah, the answer is A
 
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Zishi said:
hassam said:
1st one is A....2nd one b so zishi got 1 rong
Is ever enthalpy change of formation of HI exothermic? :eek: IT IS endothermic.

Charge density: -ve charge/volume

As negative charge decreases down the group and volume increases, so charge density has to decrease. Let me confirm it...

formation
1/2H2 + 1/2I2 -> HI
bond energy = broken - formed
= ( 218 + 75.5) - ( 299)
= -5.5 EXOTHERMIC!!!
 
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Xthegreat said:
Zishi said:
hassam said:
1st one is A....2nd one b so zishi got 1 rong
Is ever enthalpy change of formation of HI exothermic? :eek: IT IS endothermic.

Charge density: -ve charge/volume

As negative charge decreases down the group and volume increases, so charge density has to decrease. Let me confirm it...

formation
1/2H2 + 1/2I2 -> HI
bond energy = broken - formed
= ( 218 + 75.5) - ( 299)
= -5.5 EXOTHERMIC!!!
Then I guess I shouldn't reply on CIE endorsed book - in it it is given as +11kJmol^-1
 
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772
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Xthegreat said:
Zishi said:
hassam said:
1st one is A....2nd one b so zishi got 1 rong
Is ever enthalpy change of formation of HI exothermic? :eek: IT IS endothermic.

Charge density: -ve charge/volume

As negative charge decreases down the group and volume increases, so charge density has to decrease. Let me confirm it...

formation
1/2H2 + 1/2I2 -> HI
bond energy = broken - formed
= ( 218 + 75.5) - ( 299)
= -5.5 EXOTHERMIC!!!

Well, it IS ENDOTHERMIC...See wikipedia: http://en.wikipedia.org/wiki/Standard_e ... a_table%29
 
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