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Chemistry: Post your doubts here!

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http://www.xtremepapers.com/papers/... AS Level/Chemistry (9701)/9701_w10_qp_12.pdf
Q34..after 20 mins rxn is complete..mass of mg used is same so how can sukfuric acid produce more gas? statement 3 is correct according to ms..how?
Answer for question 35
the reactions will be
Mg + 2 CH3COOH <=> Mg(CH3COO)2+ H2(g)
Mg + H2SO4 → MgSO4 + H2


1 After 2 minutes, the sulfuric acid is at a higher temperature than the ethanoic acid.
2 After 2 minutes, the sulfuric acid has produced more gas than the ethanoic acid.
this is because the sulfuric acid is a stronger oxidising agent and therefore will be quicker in forming the magnesium sulfate and hydrogen than ethanoic acid .and when it does form , bond forming is exxothermic and so it is at an higher temperature
3 After 20 minutes, the sulfuric acid has produced more gas than the ethanoic acid.
This is because the reaction between ethanoic acid and magnesium is in equilibrium which means the reaction never reaches completion.Moreover , the stoichichemtry of the equilibrium shows us that more reactants are present than products (reactants =3m products =2m)
 
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17 Which statement explains the observation that magnesium hydroxide dissolves in aqueous ammonium chloride, but not in aqueous sodium chloride?

AThe ionic radius of the NH4+ ion is similar to that of Mg2+ but not that of Na+.
BNH4Cl dissociates less fully than NaCl.
CThe ions Na+ and Mg2+ are isoelectronic (have the same number of electrons).
DThe ion NH4+ acts as an acid.


Ans: D

Can someone please explainn? :) thanks in advance
 
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yield = Actual yield/measured yield x100 right?
we know there is 30 g of ethanoic acid
so Measured yield = 30(98)/60 x100 = 45 , closest to 50 so answer is C
 
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17 Which statement explains the observation that magnesium hydroxide dissolves in aqueous ammonium chloride, but not in aqueous sodium chloride?

AThe ionic radius of the NH4+ ion is similar to that of Mg2+ but not that of Na+.
BNH4Cl dissociates less fully than NaCl.
CThe ions Na+ and Mg2+ are isoelectronic (have the same number of electrons).
DThe ion NH4+ acts as an acid.


Ans: D

Can someone please explainn? :) thanks in advance

MgOH is basic, so the ammonium chloride neutralizes it, since it's acidic.
 
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Answer for question 35
the reactions will be
Mg + 2 CH3COOH <=> Mg(CH3COO)2+ H2(g)
Mg + H2SO4 → MgSO4 + H2


1 After 2 minutes, the sulfuric acid is at a higher temperature than the ethanoic acid.
2 After 2 minutes, the sulfuric acid has produced more gas than the ethanoic acid.
this is because the sulfuric acid is a stronger oxidising agent and therefore will be quicker in forming the magnesium sulfate and hydrogen than ethanoic acid .and when it does form , bond forming is exxothermic and so it is at an higher temperature
3 After 20 minutes, the sulfuric acid has produced more gas than the ethanoic acid.
This is because the reaction between ethanoic acid and magnesium is in equilibrium which means the reaction never reaches completion.Moreover , the stoichichemtry of the equilibrium shows us that more reactants are present than products (reactants =3m products =2m)
how do u knw its in equilibrium?
 
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17 Which statement explains the observation that magnesium hydroxide dissolves in aqueous ammonium chloride, but not in aqueous sodium chloride?

AThe ionic radius of the NH4+ ion is similar to that of Mg2+ but not that of Na+.
BNH4Cl dissociates less fully than NaCl.
CThe ions Na+ and Mg2+ are isoelectronic (have the same number of electrons).
DThe ion NH4+ acts as an acid.


Ans: D

Can someone please explainn? :) thanks in advance
Very simple
Mg(OH)2 is a base and it will react with an acid
It will not react with NaCl as it is not an acid
It reacts with NH4Cl because it acts as an acid because NH4+ ion donates a proton (Bronsted Lowry acid)
 
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