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Chemistry: Post your doubts here!

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Do try to include the answers next to your selected questions, it would make it easier for us to reply. :)

Q8. To find the "heaviest atmosphere", we can use the weighted average of the Mr.
Using option D as example.
Weighted Mr of D
= 0.825 x Mr of H2 + 0.152 x Mr of He + 0.023 x Mr of CH4
=0.825 x 2+ 0.152 x 4 + 0.023 x 16
= 2.63

Work out the other 3 options, the highest one is the most dense.

Q9.

View attachment 44395


Q13.
White precipitate means it forms an insoluble sulfate, which would be barium sulfate.

Q16.
Reaction 1: O.S of sulfur +6 (in H2SO4) --> +6 (in K2SO4), no change
Reaction 2: O.S of sulfur +6 --> +4 (in SO2) , change of 2 units
Reaction 3: O.S of sulfur +6 (in H2SO4) --> -2 (in H2S), change of 8 units

Q17. Ammonium chloride solution is slightly acidic as the NH4+ can donate protons (acidic), so it reacts with the alkaline magnesium hydroxide.

Q20.
1st reaction: oxidation (loss of H)
2nd reaction: nucleophilic addition (the lone pair on OH attracts the slightly positive carbon on the aldehyde)
3rd reaction : oxidation (loss of H)
Thnx man
It was very helpful (y)(y)
Sure,next time i will post the answer :D
 
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http://papers.xtremepapers.com/CIE/Cambridge International A and AS Level/Chemistry (9701)/9701_w11_qp_12.pdf Q3 ans D ,Q26 ansA , Q31 ansA , Q35 AnsB , Q36 ansD Q37 ansD please help if you can
w11qp12

Q3.
Cl- : 1s2 2s2 2p6 3s2 3p6
F- : 1s2 2s2 2p6
K+ : 1s2 2s2 2p6 3s2 3p6
Na+ : 1s2 2s2 2p6

We need to focus on F- and Na+ as the electrons removed are from a shell nearer to the nucleus.
Between F- and Na+, Na+ has more protons, so will hold on to its electrons more tightly.

Q26.
C2H5OH --> CH3CHO (note that aldehyde is collected, not acid)

mass of C2H5OH converted = 2.30 x 0.7 = 1.61 g
moles of C2H5OH converted = 1.61/46 = 0.035 mol
moles of CCH3CHO formed = 0.035 mol
mass of CH3CHO formed = 0.035 x 44 = 1.54 g

Q31.
Picture 3.png

Q36.
X is actually N2.
X--> Y--> Z
N2 --> NO --> NO2

Q37. C4H10O , note that the C4H10 is following the general formula CnH2n+2, so it means that the carbon are all single bonded. The oxygen atom would be part of an alcohol group and not ketone/aldehyde.

Since not ketone/aldehyde, we will not get observation 1.
If tertiary alcohol, we will get observation 2.
If primary or secondary alcohol, we will get observation 3.
 
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Q5. The molecule is not symmetrical, you have to view it in its 3D shape, it is tetrahedral.

Q6. MgCl2 dissolves, SiCl4 hydrolyses.

Q23. Each carbon has 4 single bonds, they are tetrahedral shape around each carbon.

Q36. NH3 accepts a H+ to form NH4+, it is a proton acceptor (base)

Q39.
H2SO4 (acid) donates a proton to C2H5OH.

Q23, The carbons are in a row like -C-C-C which is 180 right.

I know the bonds are tetrahedral but the C row has a 180 angle right?
 
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Help with this one plz, ans is B
04601-9711aa28-3732-4207-a83d-2d39684041d5.png
 
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Help with this one plz, ans is B
04601-9711aa28-3732-4207-a83d-2d39684041d5.png
Step 1: Count the hydrogen atoms in the side-chains.
Upper side-chain and lower side-chain: 2 x (3+6+6+14) = 58
Middle side-chain: 3 + 6 + 6 + 14 = 29

Step 2: Count the hydrogen atoms in each residue
First residue: 3 + 8 + 6 + 14 = 31
Second residue x 2 (because two side-chains are converted): 2 x (3 + 14 + 2 + 14) = 66

Step 3: Calculate how many hydrogen atoms had to be added to each side-chain in order to form the residues.
Upper and lower side-chain residues have 66 - 58 extra hydrogens = 8 extra hydrogens
Middle side-chain residue has 31-29 extra hydrogens = 2 extra hydrogens

Step 4: You know that 10 hydrogen atoms have been added to the original molecule. Each hydrogen molecule contains two hydrogen atoms, so there are 10/2 = 5 hydrogen molecules ie. 5 moles of hydrogen
 
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