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Chemistry: Post your doubts here!

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June 13 P41, 1) c) ii)
mark scheme ays its forward (more product) because E is more than 0 (its positive)
but isnt that always the case ?? Even if both half cells is negative its going to be (-0.12)-(-0.67)= positive??
so why are there more products?
 
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Any advice on how to study whole chemistry in 2 weeks? I have done Maths and Physics with past papers just left with chem. Any advice or links/pdfs/pics/notes would be really helpful.
 
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June 13 P41, 1) c) ii)
mark scheme ays its forward (more product) because E is more than 0 (its positive)
but isnt that always the case ?? Even if both half cells is negative its going to be (-0.12)-(-0.67)= positive??
so why are there more products?
If E cell is positive then the reaction will be proceeding in forward direction. This means more products will be formed.
 
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Can someone help me with chemistry paper 5 Oct Nov 2014 var 52 Q1 part d subpart I and ii. How to compare the concentrations or molecules?
 
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June 13 P41, 1) c) ii)
mark scheme ays its forward (more product) because E is more than 0 (its positive)
but isnt that always the case ?? Even if both half cells is negative its going to be (-0.12)-(-0.67)= positive??
so why are there more products?
wait i dont get how E cell can be negative LOL :D
How can E cell be negative?
I realised.
Can you explain why having a positive E cell mean there are more products?
Ecell will be positive for reactions which are feasible/spontaneous in the forward direction. If Ecell is negative then the reaction is feasible only for the backward direction.

Since you calculated that Ecell was positive then the reaction:
2Fe + 2I <=> 2Fe+ I 2
Will only occur in the forward direction: 2Fe + 2I => 2Fe+ I 2

If Ecell was negative then the reaction would only occur in backward direction: 2Fe+ I 2 => 2Fe + 2I

MS is talking about Ecell and not E.
 
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Messages
2,206
Reaction score
2,824
Points
273
I realised.
Can you explain why having a positive E cell mean there are more products?
wait i dont get how E cell can be negative LOL :D
How can E cell be negative?
Ecell will be positive for reactions which are feasible/spontaneous in the forward direction. If Ecell is negative then the reaction is feasible only for the backward direction.

Since you calculated that Ecell was positive then the reaction:
2Fe + 2I <=> 2Fe+ I 2
Will only occur in the forward direction: 2Fe + 2I => 2Fe+ I 2

If Ecell was negative then the reaction would only occur in backward direction: 2Fe+ I 2 => 2Fe + 2I

MS is talking about Ecell and not E.
As TariqBhai explained, if Ecell value is positive means reaction will be occurring. As reaction is occurring that simply means reaction is moving in forward direction. This means more product. And the reaction which arent feasible are the ones that have negative Ecell and the reaction will move backwards.
 
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