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Ohk if were taking the view of diffusion here let be clearify . The total available volume of gas is 200cm3 . and on the right side is 100 cm3 of vacum . At best you'd get 100cm3 on right and 100cm3 on the left . YOU CAN NOT GET 300cm3 of gas when there is only 200 cm3 of gas available .
You got it wron gas takes the volume of container it doesnt have fixed volum