• We need your support!

    We are currently struggling to cover the operational costs of Xtremepapers, as a result we might have to shut this website down. Please donate if we have helped you and help make a difference in other students' lives!
    Click here to Donate Now (View Announcement)

Chemistry: Post your doubts here!

Messages
382
Reaction score
315
Points
73
Can anyone explain to me why change in pressure won't affect equilibrium constant?
Equilibrium constant does not change when you change the pressure of a system. The only factor that affects the equilibrium constant is temperature.
The equilibrium constant is just a ratio of the product of the products to the product of the reactants.. right? Now increasing the pressure of the reactant unbalances the equilibrium because more products are formed. The concentration of products will increase until a new equilibrium is reached when the value of the equilibrium constant gets back to what it was before (The value remains the same).

In conclusion, the equilibrium "constant" is always constant unless the pressure is changed.
 
Messages
221
Reaction score
203
Points
53
Hi, I need someone to explain the mechanism for addition oxidation of alkenes. My teacher told me a different mechanism then the one shown in the notes section of XP.....and I am confused between the two....:(
If someone could give me a step by step explanation of exactly what happens that would be very helpful....:)
 
Messages
114
Reaction score
36
Points
38
And can anyone on Earth tell me what am I missing in this question?
The refrence is 9701/12/M/J/11 [ U can check the markscheme, the answer is A. How is 1 correct ?!!!
View attachment 23077
nitrogen is been reduced because see the oxidation number of nitrogen in NCl3 nitrogen oxidation number is +3 and nitrogen oxidation number in N2 is 0 therefore nitrogen has gained electrons and we know that gaining electrons is reduction :)
 
Messages
114
Reaction score
36
Points
38
O/N 11/12 question 3
Can anyone who is good in chemistry solve this?
Use of the Data Booklet is relevant to this question.
From which particle is the removal of an electron the most difficult?
A Cl- (g) B F- (g) C K+ (g) D Na+ (g)
check out the ionisation energy values the element which has the highest value .. so d is the answer because Na+ has the highest value
 
Messages
19
Reaction score
3
Points
13
The reaction of hydrogen sulphide with sulfur dioxide gives sulphur as one of the products. h
H2S(aq) < -------> 2H2+(aq) +2e+S(s)
SO2(aq)+ 4H2+4e< -------> S(s) +H2O
how many moles of hydrogen sulphide are neede to react with sulphur dioxide to produce 1mole of sulphur ?
Help?
a- 1/3 mol
b-2/3 mol
c-3/2 mol
d-2 mol
 
Messages
3,937
Reaction score
14,646
Points
523
8 (a) Electrophoresis can be used to separate amino acids which are produced by the
hydrolysis of a polypeptide.
Using glycine as an example, explain why the result of electrophoresis depends on pH.
qp so7
sm1 plz state d logic :confused:
 
Messages
279
Reaction score
80
Points
38
The reaction of hydrogen sulphide with sulfur dioxide gives sulphur as one of the products. h
H2S(aq) < -------> 2H2+(aq) +2e+S(s)
SO2(aq)+ 4H2+4e< -------> S(s) +H2O
how many moles of hydrogen sulphide are neede to react with sulphur dioxide to produce 1mole of sulphur ?
Help?
a- 1/3 mol
b-2/3 mol
c-3/2 mol
d-2 mol

i think the answer should be D i.e 2 moles
 
Messages
279
Reaction score
80
Points
38
cmon ofcourse ichecked d mark scheme..!! ididnt get a wrd..!!pchhh...nai smajh ra he...:(

chalo i am giving it a try

amino acids contain the -NH2 group . when the solution is acidic (i.e H+ ions are present), nitrogen in the the -NH2 group uses iits lone pair of electrons and attracts the H+ ion.. a dative covalent bond is formed and the charge on the molecule is is increased by +1 so the spot moves towards the negative electrode(cathode)

in case the solution becomes more alkaline, the COOH ggroup loses its hydrogen in the form of H+ ions to nuetralise the ffect of base (OH- ions and H+ ions react to form water)
but the charge on the original molecule has decreased by 1 , it is attarcted to the anode (pos. electrode)

This way electrophoresis is dependant on the pH
 
Top