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Chemistry: Post your doubts here!

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please help me with Q20 with explanation.
it says that there is an aldehyde group and cyclo hexene so C6H10 + CHO = C7H11O
The real moleculer formula is C20H28O...C20 -C 7= C13....
Now,there iz a long aliphatic chain...general formula is CnH2n+2...so C13H28...
for each double bond formation a hydrogen molecule is removed...so if there iz 5 double bond means ...5*2=10 H is removed...
SO OUT OF 28 H in C13H28...28-10=18 is remained...but 1 more H is removed due to attachment...
 
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View attachment 8865
it says that there is an aldehyde group and cyclo hexene so C6H10 + CHO = C7H11O
The real moleculer formula is C20H28O...C20 -C 7= C13....
Now,there iz a long aliphatic chain...general formula is CnH2n+2...so C13H28...
for each double bond formation a hydrogen molecule is removed...so if there iz 5 double bond means ...5*2=10 H is removed...
SO OUT OF 28 H in C13H28...28-10=18 is remained...but 1 more H is removed due to attachment...


Thanks so much! :D
 
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Apologies. Q.6...
no problem ;)

calculate the oxidation nos of Cr in all the equations
A) +6 ----> +3
B) +6 ---->+6
C) +6 ----> +6
D) +6 ----> +3

Answer is D because the no of O (per Cr atom) is also reducing along with the ON.. this was the explanation i was given by someone... I'd like it if u guys could confirm please
 
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Use of the Data Booklet is relevant to this question.
Lead(IV) chloride will oxidise bromide ions to bromine. The Pb4+ ions are reduced to Pb2+ ions in
this reaction.
If 6.980 g of lead(IV) chloride is added to an excess of sodium bromide solution, what mass of
bromine would be produced?
A 0.799 g B 1.598 g C 3.196 g D 6.392 g

The answer is C ?? explain someone!
 
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Use of the Data Booklet is relevant to this question.
Lead(IV) chloride will oxidise bromide ions to bromine. The Pb4+ ions are reduced to Pb2+ ions in
this reaction.
If 6.980 g of lead(IV) chloride is added to an excess of sodium bromide solution, what mass of
bromine would be produced?
A 0.799 g B 1.598 g C 3.196 g D 6.392 g

The answer is C ?? explain someone!
AoA,
The key to solving this question is forming the equation
PbCl4 + 2NaBr ------> PbCl2 + Br2 + 2NaCl

Mr(lead chloride) = 207 + 4(35.5) = 349
moles of lead chloride = 6.980 / 349 = 0.02 mol

Since molar ratio b/w lead chloride and Br2 is 1:1
moles of Br2 = 0.02
mass of Br2
= 0.02 * Mr
= 0.02 * (2 * 79.9)
= 3.196

C is the answer!
 
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Use of the Data Booklet is relevant to this question.
Lead(IV) chloride will oxidise bromide ions to bromine. The Pb4+ ions are reduced to Pb2+ ions in
this reaction.
If 6.980 g of lead(IV) chloride is added to an excess of sodium bromide solution, what mass of
bromine would be produced?
A 0.799 g B 1.598 g C 3.196 g D 6.392 g

The answer is C ?? explain someone!
equation:- PbCl4+2NaBr----->Br2+ other stuff
mol of PbCl4=mol of Br2
6.980 mass
------------------ = -----------------
(207+(35.5*4) 79.9 *2
furthur solve it you will get the answer 3.196
 
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Use of the Data Booklet is relevant to this question.
A 5.00 g sample of an anhydrous Group II metal nitrate loses 3.29 g in mass when heated
strongly.
Which metal is present?
A magnesium
B calcium
C strontium
D barium

Ans is B ? There are many such Q's in the past papers. i dont know how to do it !?
 
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Use of the Data Booklet is relevant to this question.
A 5.00 g sample of an anhydrous Group II metal nitrate loses 3.29 g in mass when heated
strongly.
Which metal is present?
A magnesium
B calcium
C strontium
D barium

Ans is B ? There are many such Q's in the past papers. i dont know how to do it !?
let metal be X

2X(NO3)2 --> 2XO + 4NO2 + O2
5g ............ --> 1.71g +[ 3.29g ]

Mass of 1 mole of (4no2+ o2)=216grams
There are 3.29/216 moles of (4no2+o2)present
Also 3.29/216 moles of 2XO present
Therefore there is (2*3.29)/216 moles of XO
molar mass of XO = g/mol= 1.71/[(2*3.29)/216]=56.1grams
X=56.1-16=40.1 grams permole
Therefore answer is:

B.Calcium
 
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let metal be X

2X(NO3)2 --> 2XO + 4NO2 + O2
5g ............ --> 1.71g +[ 3.29g ]

Mass of 1 mole of (4no2+ o2)=216grams
There are 3.29/216 moles of (4no2+o2)present
Also 3.29/216 moles of 2XO present
Therefore there is (2*3.29)/216 moles of XO
molar mass of XO = g/mol= 1.71/[(2*3.29)/216]=56.1grams
X=56.1-16=40.1 grams permole
Therefore answer is:

B.Calcium

How did you get the 216g from ?
 
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