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Chemistry: Post your doubts here!

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GUYSSSS. Gotta help me with this, PLEASEEE. hahahaha
Must be very easy for you guys! :cool:
Anyways, okay.
http://papers.xtremepapers.com/CIE/... AS Level/Chemistry (9701)/9701_w13_qp_13.pdf
Q27 (C)

http://papers.xtremepapers.com/CIE/... AS Level/Chemistry (9701)/9701_w13_qp_12.pdf
Q8 (D) [ i guess all these answers correctly, but i dont understand why ]

http://papers.xtremepapers.com/CIE/... AS Level/Chemistry (9701)/9701_w11_qp_12.pdf
Q24 (B) , Q26 (A), Q30 (A)

THANK YOU SO SO MUCHHHHHH!! please help :D
the same questions are asked again and again.
27:
the alcohol is tertiary and have a chiral carbon with least number of carbons: so chiral carbon has one CH3 one OH one C2H5 and one C3H7 attached to it. this is the only way to make the n smallest and still have a teriary alcohol with chiral carbon
8:density depends on Mr. the average Mr of D looks high as it has highest percentage of CH3.
24:
CH3CHO→CH3CH(OH)CN->CH3CH(OH)CO2H→CH3CH(OH)CO2CH3(esterification)
 
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calculate energy needed to break the bonds - energy released when bonds formed . the most negative asnwer on the right side and most positive to the left side. example:
in P: Br-Br is brocken and no bond is made so 193-0=+193
in Q: no bonds are broken only bond make is Cl-Cl so 0-244=- 244
in R CH3 + cl → CH3Cl only bond made is C-Cl. so -340
in S only bond broken is C-H = +410
negtive →→→ postive
-340(R) → -244(Q) → +193 → 410(S)
Thank u brother
 
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in 36 spontenously means 'by itself' it means that unlike SO2→SO3 which needs a catalyst it happens naturally. so it must be NO→NO2
Nitrogen has two of it's electron bonded. rest of the three are like 2 paired and one unpaired.

39:
in (2) the ester will hydrolyse to form ethanoic acid and methanol. in (3) the nitrile will hydrolyse with alkali to make CH3CO2 and with H+ it will make ethanoic acid too. in (1) substituition or elimination will take place with aqueous OH
 
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Someone please explain these 3 to me
 

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in 36 spontenously means 'by itself' it means that unlike SO2→SO3 which needs a catalyst it happens naturally. so it must be NO→NO2
Nitrogen has two of it's electron bonded. rest of the three are like 2 paired and one unpaired.

39:
in (2) the ester will hydrolyse to form ethanoic acid and methanol. in (3) the nitrile will hydrolyse with alkali to make CH3CO2 and with H+ it will make ethanoic acid too. in (1) substituition or elimination will take place with aqueous OH

Thanks alot
 
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the same questions are asked again and again.
27:
the alcohol is tertiary and have a chiral carbon with least number of carbons: so chiral carbon has one CH3 one OH one C2H5 and one C3H7 attached to it. this is the only way to make the n smallest and still have a teriary alcohol with chiral carbon
8:density depends on Mr. the average Mr of D looks high as it has highest percentage of CH3.
24:
CH3CHO→CH3CH(OH)CN->CH3CH(OH)CO2H→CH3CH(OH)CO2CH3(esterification)

Thank you so much suchal riaz! :D and sorry for bothering you.

http://papers.xtremepapers.com/CIE/... AS Level/Chemistry (9701)/9701_w11_qp_12.pdf
Q26 (A), Q30 (A)

THANK YOU SO SO MUCHHHHHH!! please help :D
 
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http://papers.xtremepapers.com/CIE/Cambridge International A and AS Level/Chemistry (9701)/9701_s12_qp_12.pdf
Q6-c ( i got D 21.6 i did the calculation twice got 0.06 mol 7dm^3 and temp 303 n calcultaed it using them )
Q20-c (plz write the calculation)
Q24-A ( octene ha c8h18 so wen it cracks the products will add up to be with in the molecular formula of octene ryt)
Thanks.
number of moles = 0.96/32=0.03 moles
P=nRT/V=.03moles*8.31*(273+30)K / 7000x10^-6 m²=10.7KPa
 
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